黏土矿物有机硅烷改性研究进展
第39卷第1期2019年2月
矿产保护与利用
CONSERVATION AND UTILIZATION OF MINERAL RESOURCES
Vol.39, .1
Feb.2019黏土矿物有机硅烷改性研究进展*
苏琳娜
(深圳职业技术学院应用化学与生物技术学院,广东深圳518055)
摘要:黏土矿物由于具有独特的层状纳米结构特性,在基础研究和实际应用中引起人们普遍的关注三但黏
土矿物的亲水性表面使其对材料性能的提升产生限制,因此采用有机硅烷对黏土矿物进行表面改性是改善
黏土矿物表面性质的有效方法之一三经过有机硅烷改性的黏土矿物既具有黏土矿物特有的尺寸稳定性二吸
附性和阻隔性等性能,又具有硅烷分子多种功能基团的反应活性,在聚合物纳米复合材料二载体材料和环境
材料等领域具有广阔的应用前景,已成为近年来矿物学和材料科学的研究热点之一三综述了不同类型黏土
矿物有机硅烷改性的研究进展,讨论了黏土矿物类型二有机硅烷种类和反应条件对改性黏土矿物结构的影
响,同时对黏土矿物有机硅烷改性未来主要研究方向进行展望三
关键词:黏土矿物;蒙脱石;高岭石;有机硅烷;改性
中图分类号:TD985 文献标识码:A 文章编号:1001-0076(2019)01-0124-07
DOI：10.13779/https://www.wendangku.net/doc/204110282.html,ki.issn1001-0076.2019.01.023
Research Progress in Organosilane Modification of Clay Minerals
SU Linna
(School of Applied Chemistry and Biological Technology,Shenzhen Polytechnic,Shenzhen518055,China) Abstract：Clay minerals have attracted considerable attention in basic research and practical appli-
cations due to their unique layered nanostructure.However,the hydrophilic surface of clay minerals
makes it difficult to improve the properties and limits the application of materials.Therefore,the sur-
face modification with organosilane is one of the effective methods to improve the surface properties of
clay minerals.The clay minerals modified by organosilane possess dimensional stability,adsorptivity
and barrier properties of clay minerals,and high reactivity of various functional groups in organosi-
lane molecules.Therefore,the modified clay minerals have wide applications in materials science,
environmental engineering and carrier materials.Accordingly,they have attracted much attention in
mineralogy and material science in recent years.This paper reviewed the research progress in or-
ganosilane modification of clay minerals with different types.The influence of clay mineral type,or-
ganiosilane species and reaction conditions on the structure of modified clay minerals was discussed,
and the main research directions of organosilane modification of clay minerals were prospected.
Key words：clay minerals;montmorillonite;kaolinite;organosilane;modification
引言
在众多无机纳米粒子中,由于黏土矿物具有独特的天然纳米片层结构,其以纳米单元体分散在聚合物中,可以显著提高复合材料的热学性能二力学性能和阻隔性等’1-6]三但是黏土矿物的表面呈现亲水
*收稿日期:2018-06-28
基金项目:深圳职业技术学院科研基金(6017-22K210169991)
作者简介:苏琳娜(1984-),女,福建三明人,博士,讲师,主要从事矿物材料与矿物表-界面反应性研究,E-mail：sln0598＠https://www.wendangku.net/doc/204110282.html,三
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