英文-水泥外加剂(甲酸钙)MSDS

Material Safety Data Sheet

Calcium formate, 98% (titr.)

MSDS Name: Calcium formate, 98% (titr.)

Catalog Numbers: AC403830000, AC403830010, AC9618663, XXAC4038325K Synonyms: Calcium diformate; Calcoform; Formic acid, calcium salt; Company Identification:

Fisher Scientific

1 Reagent Lane

Fair Lawn, NJ 07410

For information, call: 201-796-7100

Emergency Number: 201-796-7100

For CHEMTREC assistance, call: 800-424-9300

For International CHEMTREC assistance, call: 703-527-3887

EMERGENCY OVERVIEW

Appearance: clear colorless powder.

Warning! Causes eye, skin, and respiratory tract irritation.

Target Organs: Respiratory system, eyes, skin.

Potential Health Effects

Eye: Causes eye irritation.

Skin: Causes skin irritation.

Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes irritation of the mucous membrane and upper respiratory tract. Chronic: No information found.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Notes to Physician: Treat symptomatically and supportively.

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.

Extinguishing Media: In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.

Flash Point: Not applicable.

Autoignition Temperature: Not applicable.

Explosion Limits, Lower:Not available.

Upper: Not available.

NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0

General Information: Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation.

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Storage: Store in a tightly closed container. Store in a cool, dry area away from incompatible substances.

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.

Exposure Limits

OSHA Vacated PELs: Calcium formate: No OSHA Vacated PELs are listed for this chemical.

Personal Protective Equipment

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR

1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Physical State: Powder

Appearance: clear colorless

Odor: slight acetic acid odor

pH: Not applicable.

Vapor Pressure: Not available.

Vapor Density: Not available.

Evaporation Rate:Not available.

Viscosity: Not available.

Boiling Point: Not available.

Freezing/Melting Point:> 300 deg C

Decomposition Temperature:Not available.

Solubility: soluble in water

Specific Gravity/Density:2.02

Molecular Formula:C2H2CaO4

Molecular Weight:130.11

Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials.

Incompatibilities with Other Materials: None reported.

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Will not occur.

RTECS#:

CAS# 544-17-2: LQ5600000

LD50/LC50:

CAS# 544-17-2:

Draize test, rabbit, eye: 100 mg/24H Moderate;

Oral, mouse: LD50 = 1920 mg/kg;

Oral, rat: LD50 = 2650 mg/kg;

.

Calcium formate @ 0.2 ppm for 2 years in rat drinking water did not affect growth, fertility, or function in up to 5

Carcinogenicity:

CAS# 544-17-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.

Teratogenicity: No information available.

Reproductive Effects: No information available.

Mutagenicity: No information available.

Neurotoxicity: No information available.

Other Studies:

Ecotoxicity: No data available. No information available.

Environmental: No data available.

Physical: No data available.

Other: None.

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

US FEDERAL

TSCA

CAS# 544-17-2 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule. Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

CERCLA Hazardous Substances and corresponding RQs

None of the chemicals in this material have an RQ.

SARA Section 302 Extremely Hazardous Substances

None of the chemicals in this product have a TPQ.

SARA Codes

CAS # 544-17-2: immediate.

Section 313 No chemicals are reportable under Section 313.

Clean Air Act:

This material does not contain any hazardous air pollutants.

This material does not contain any Class 1 Ozone depletors.

This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

None of the chemicals in this product are listed as Hazardous Substances under the CWA.

None of the chemicals in this product are listed as Priority Pollutants under the CWA.

None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA. STATE

CAS# 544-17-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols:

XI

Risk Phrases:

R 36/38 Irritating to eyes and skin.

Safety Phrases:

S 26 In case of contact with eyes, rinse immediately with plenty of

water and seek medical advice.

S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection)

CAS# 544-17-2: 1

Canada - DSL/NDSL

CAS# 544-17-2 is listed on Canada's DSL List.

Canada - WHMIS

This product has a WHMIS classification of D2B.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.

Canadian Ingredient Disclosure List

CAS# 544-17-2 is listed on the Canadian Ingredient Disclosure List.

MSDS Creation Date: 6/16/1999

Revision #4 Date: 3/15/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for

any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.