Tinuvin XT 850
TINUVIN XT 850 FF Revision 20.02.2003
(dd.mm.yyyy)
1. Identification of the Substance/Preparation and the Company/Undertaking
Product name TINUVIN XT 850 FF
Chemical identification HALS light stabilizer mixture
CAS Number Preparation
Use Stabiliser
Producer/Supplier CIBA SPECIALTY CHEMICALS PLC
CHARTER WAY
MACCLESFIELD CHESHIRE SK10 2NX
GREAT BRITAIN
Phone Number +44 (0)1625 665000
Telefax
Emergency Phone Number (24h) +44 (0)1625 616008
2. Composition/Information on Ingredients
Substances presenting a health or environmental hazard
Number Chemical Name Content Symbol(s) R-Phrase(s) EC-Number CAS
High molecular weight hindered amine light
20 - 60 % Xi - N R43 - R51/53
stabilizer
Sterically hindered amine light stabilizer 20 - 60 % R53
3. Hazards Identification
Classified as hazardous according the EU directives.
Xi Irritant
N Dangerous for the environment
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. First Aid Measures
Skin contact
Wash off with soap and plenty of water. Do not use organic solvents. In case of dermatitis, seek medical attention.
Eye contact
Rinse immediately with plenty of water for at least 15 minutes. In case of eye irritation, seek medical attention. Inhalation
Move to fresh air. In case of irritation of respiratory system or mucous membranes, seek medical attention. In case of indisposition, seek medical attention. In case of prolonged exposure, seek medical attention.
Ingestion
Immediately give plenty (> 500 ml) of water (if possible charcoal slurry). In case of spontaneous vomiting be sure that vomitus can freely drain due to danger of suffocation. Give water repeatedly. Artificial induction of vomiting should be restricted to first aid staff. Give nothing by mouth in cases of unconsciousness or convulsion. Seek medical advice.
5. Fire-Fighting Measures
Suitable extinguishing media
Water spray, Carbon dioxide (CO2), Foam, Dry powder
Extinguishing media which must not be used for safety reasons
High volume water jet
Exposure hazards
Contaminated water from fire hoses or sprinklers, etc., must be prevented from draining into watercourses, sewers, or
TINUVIN XT 850 FF Revision 20.02.2003
(dd.mm.yyyy) the ground water. Sufficient measures must be taken to retain water used for extinguishing. Contaminated water and soil must be disposed of in conformity with local regulations.
Special protective equipment for firefighters
Wear full protective clothing. Wear self-contained breathing apparatus.
Combustion products
Oxides of carbon; Oxides of nitrogen (NOx); Toxic gases/vapours
6. Accidental Release Measures
Personal precautions
Do not breathe vapours/dust. Remove all sources of ignition. Avoid contact with skin, eyes and clothing. Environmental precautions
Do not flush into surface water, sanitary sewer or ground water system.
Methods for cleaning up
Use mechanical handling equipment. Collect the spilled product into suitable containers, which must be tightly sealed and properly labelled. Avoid dust formation.
7. Handling and Storage
Handling
Sensitizing. Handle and open container with care. Avoid dust formation and ignition sources. Ensure good local exhaust ventilation. Do not eat, drink or smoke at the workplace.
Storage
Keep away from food and drink. Store in the original container securely closed.
Caution, keep this product well sealed. Keep in cool, dry place. Close containers immediately after use.
8. Exposure Controls / Personal Protection
Exposure limit(s)
CIEL-TWA Ciba internal exposure limit (8 hour time weighted average)
not tested
Technical measures/Precautions
No special precautions required.
Respiratory protection
Effective dust mask.
Hand protection
Protective gloves
Eye protection
Suitable goggles or face protection
Skin and body protection
Working clothes , Closed footwear
9. Physical and Chemical Properties
Form granules
Form granular
Colour white to off-white
Odour odourless
tested
Melting/freezing temperature not
applicable
Boiling point/range not
tested
Relative density not
tested
Flash point not
tested
Ignition Temperature not
Oxidising properties not
tested
tested
Self-ignition temperature not
tested
Water solubility not
TINUVIN XT 850 FF Revision 20.02.2003
(dd.mm.yyyy) Vapour pressure not
tested
Partition coefficient; Log Pow not
tested
pH-value not
tested
Explosive properties not
tested
10. Stability and Reactivity
Decomposition temperature not
tested
Conditions to avoid Static
discharges.
Materials to avoid Strong acids, strong bases and
strong oxidising agents.
Hazardous decomposition products Oxides of carbon, Oxides of
nitrogen (NOx), Toxic
gases/vapours
11. Toxicological Information
Acute oral toxicity Rat LD50 > 2000 mg/kg Conventional
Method
Acute dermal toxicity not tested Acute Inhalation Toxicity not tested
Acute eye irritation/corrosion Rabbit not irritant Conventional
Method
Acute dermal irritation/corrosion Rabbit not irritant Conventional
Method
Acute skin sensitisation Guinea pig sensitising Conventional
Method
12. Ecological Information
Acute toxicity to fish not tested Acute toxicity to daphnia not tested Acute toxicity to bacteria not tested Acute toxicity to algae not tested Biodegradability not tested Ecotoxic effects
Do not discharge product uncontrolled into the environment.
TINUVIN XT 850 FF Revision 20.02.2003
(dd.mm.yyyy) Information on classification
This preparation is classified relating to its environmental hazards applying the conventional method described in EU Directive 1999/45/EC, Annex III.
13. Disposal Considerations
Waste from residues / unused products
Residual chemical should be disposed by incineration or by other modes of disposal in compliance with local legislation. Contaminated packaging
Contaminated packaging material should be treated equivalent to residual chemical. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation.
14. Transport Information
Flash point not tested
9
ADR/RID Class:
UN No.: 3077
Packaging group: III
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Additional Information: (HIGH MOLECULAR WEIGHT HINDERED AMINE LIGHT
STABILIZER)
IMO Class:
9
UN No.: 3077
Packaging group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Additional Information: (HIGH MOLECULAR WEIGHT HINDERED AMINE LIGHT
STABILIZER)
9
ICAO Class:
UN No.: 3077
Packaging group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Additional Information: (HIGH MOLECULAR WEIGHT HINDERED AMINE LIGHT
STABILIZER)
15. Regulatory Information
Classification Self-classification
Irritant
Symbol(s) Xi
N Dangerous for the environment
R-Phrase(s) R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-Phrase(s) S37 Wear suitable gloves.
S60 This material and/or its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/Safety data
sheets.
Contains High molecular weight hindered amine light stabilizer
TINUVIN XT 850 FF Revision 20.02.2003
(dd.mm.yyyy)
16. Other Information
R-phrases from chapter 2 R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment. Essential changes Section 2 ; Section 3 ; Section 11 ; Section 12 ; Section 14 ; Section 15 TINUVIN is a registered trademark.
Important
THIS MATERIAL IS NOT INTENDED FOR USE IN PRODUCTS FOR WHICH PROLONGED
CONTACT WITH MUCOUS MEMBRANES, BODY FLUIDS OR ABRADED SKIN, OR
IMPLANTATION WITHIN THE HUMAN BODY, IS SPECIFICALLY INTENDED, UNLESS THE
FINISHED PRODUCT HAS BEEN TESTED IN ACCORDANCE WITH NATIONALLY AND
INTERNATIONALLY APPLICABLE SAFETY TESTING REQUIREMENTS. BECAUSE OF THE
WIDE RANGE OF SUCH POTENTIAL USES, CIBA IS NOT ABLE TO RECOMMEND THIS
MATERIAL AS SAFE AND EFFECTIVE FOR SUCH USES AND ASSUMES NO LIABILITY FOR
SUCH USES.
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties.