Synthesis and Crystal Structures of Novel Keggin and Dawson Polyoxometalates Containing Amantadine

Synthesis and Crystal Structures of Novel Keggin and Dawson Polyoxometalates Containing

Amantadine

Shu Xia LIU;Chun Mei WANG;Hong Ju ZHAI;De Hui LI;En Bo WANG

【期刊名称】《中国化学快报（英文版）》

【年(卷),期】2004(015)002

【摘要】Two novel polyoxometalates containing pharmaceutical component amantadine, formulated with (C10H18N)5PMo12O40Cl2·5H2O (I) and (C10H18N) 6As2Mo18O62·6CH3CN·6H2O(II) were first synthesized and characterized by IR, UV-Vis spectra and X-ray diffraction. Structural analyses of I and II suggested that polyanions in these compounds were reserved their Keggin or Dawson structures and were linked to amantadine through electrostatic interaction and hydrogen bonding.【总页数】4页(216-219)

【关键词】Amantadine;polyoxometalate;synthesis;crystal structure

【作者】Shu Xia LIU;Chun Mei WANG;Hong Ju ZHAI;De Hui LI;En Bo WANG

【作者单位】Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024;Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024;Institute of Polyoxometalate