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ICP103450CA(20091231)

ICP103450CA(20091231)
ICP103450CA(20091231)

December 31,2009 1.Product and company information

Product name:As use Cobalt based Lithium-ion cell

Production code : EFSPE-82033、EFSPE-82036、EFSPE80057

Production model : ICP103450CA

Typical Capacity: 1960mAH / 7.25Wh

Typical V oltage : 3.7 V oltage

Names of the manufacturer or supplier:E-ONE MOLI ENERGY CORP.

Address of the manufacturer or supplier: 10F, NO.113 ,Sec.2, Zhongshan N.Rd, Taipei 104, T aiwan

R.O.C.

Phone numbers of the manufacturer or supplier:886-2-2692-6755

Emergency contact phone numbers:886-2-2567-3500#853 Steve Hsiao

Emergency contact fax numbers:886-2-2567-6500, 886-2-2567-6115

2.Hazards identification information

As a solid, these chemicals and metals are contained in a sealed can. For consumer use, exposure to hazardous in gradients is not expected with normal use. adequate hazard warnings are included on both the package and on the battery.

Do not short circuit, puncture, incinerate, crush, immerse, force discharge or expose to temperatures above the declared operating temperature range of the product. Risk of fire or explosion. Under normal conditions of use, the electrode materials and liquid electrolyte they contain are not exposed to the outside, provided the battery integrity is maintained and seals remain intact. Risk of exposure only in case of abuse (mechanical, thermal, electrolyte leakage, electrode materials reaction with moisture/ water or battery vent/ explosion/ fire may follow, depending upon the circumstance.

Hazard classification:None

3.Ingredients identification information

Component % (w/w) Exposure Limits1,2LD50LC50

Dimethyl Carbonate

(CAS No. 616-38-6)

4 - 6 Not established

13000 mg/kg

(rat/oral)

5000 mg/kg

(rabbit/dermal)

Not established

Ethylene Carbonate

(CAS No. 96-49-1)

2 -

3 Not established

10400 mg/kg

(rat/oral)

> 3000 mg/kg

(rabbit/dermal)

Not established

Lithium Hexafluorophosphate

(CAS No 21324-40-3) 1 - 3 Not established

1702 mg/kg

(rat/oral)

>20 mg/kg

(rat/4 hour)

Propylene Carbonate

(CAS No. 108-32-7) < 1.0 Not established

29100 mg/kg

(rat/oral)

>5000 mg/m3

(rat/4 hour)

1.Exposure Limits are those published by ACGIH, American Conference of Governmental Industrial Hygienists.

2.Exposure limits may vary from time to time and from one jurisdiction to another. Check with local regulatory agency for

the exposure limits in your area..

3.Production code EFSPE80057 is Halogen Free.

December 31,2009 4.The first-aid procedures

INHALA TION: Remove victim to fresh air. If breathing is difficult a trained

person may administer oxygen at a rate of 10 to 15 litres per minute. If breathing

has stopped administer artificial respiration by use of a pocket mask or bag valve

mask. Do NOT give mouth-to-mouth artificial respiration. Get medical attention

immediately .

SKIN CONTACT: Immediately wash skin with soap and copious amounts of

water for at least 15 minutes. Remove contaminated clothing and administer a

safety shower if contamination of the torso or legs above the knee has occurred.

Relief from pain and swelling may be obtained by applying topical ointments

after washing. Seek immediate medical advice if significant areas of the body

have been affected, or if a severe skin reaction occurs. Treatment must be immediate due to the formation of hydrofluoric acid on moist skin. Launder clothing before reuse and discard leather footwear. Soak permeable belongings in benzalkonium chloride after washing.

EYE CONTACT: Immediately flush eyes with large volumes of water for at

least 15 minutes, holding eyelids open while flushing. Care must be taken not to

cross contaminate the eyes. In all cases of eye contact seek immediate medical

attention. Continue to flush during transport to a medical facility .

First-aid method for different exposure routes INGESTION: Do not give anything by mouth to a victim who is either

unconscious or is losing consciousness. If swallowed, wash mouth with water and

have victim spit the wash water out. Repeat. Give one to two glasses of water to

wash the throat. Do NOT induce vomiting. If vomiting occurs naturally , have

victim lean forward to avoid aspiration. Seek medical attention.

The most important symptoms and hazardous effects :Not applicable

The protection of first-aiders Notes to physicians :If battery is leaking may extremely corrosive HF is produced upon combustion. Demand to use Ca-gluconate cream or liquid for first-aid.

5.Fire-fighting procedures

Suitable fire extinguishing media :Dry chemical, alcohol foam, water or carbon dioxide. For incipient fires, carbon dioxide extinguishers are more effective than water.

Specific hazards may be encountered during fire-fighting :T emperature over 100℃(212℉) batteries may burst and release hazardous.

Specific fire-fighting program :Rapidly cool batteries and adjacent structures with water.

Special equipment for the protection of firefighters :Use SCBA (self-contained breathing apparatus) and full protective gear.

December 31,2009 Other:(Decomposition products when exposed to a fire situation.)

This information is given for the use of professional fire fighters responding to a warehouse fire where fire from other materials may incinerate Molicels. This section is provided solely in case of exposure, during fire fighting, to the combustion by-products. Hydrofluoric acid is not present in the product. Contact with Molicels causes none of the following symptoms.

Hydrofluoric acid is extremely corrosive. Contact with hydrogen fluoride fumes is to be avoided. Permissible exposure limit is 3 ppm. In case of contact with hydrogen fluoride fumes, immediately leave the area and seek first aid and emergency medical attention. Symptoms may have delayed onset. Fluoride ions penetrate skin readily causing destruction of deep tissue layers and even bone. Fluoride interferes with nerve impulse conduction causing severe pain or absence of sensations. Immediately flush eyes or skin with water for at least 20 minutes to neutralize the acidity and remove some fluoride. Remove and destroy all contaminated clothing and permeable personal possessions.

Before re-use, impermeable possessions should be soaked in benzalkonium chloride after water washing. Following flushing of the affected areas, an iced aqueous solution of benzalkonium chloride or 2.5 % calcium gluconate gel should be applied to react with the fluoride ion. Compresses and wraps may be used for areas where immersion is not practical. Medicated dressing should be changed every 2 minutes. Exposure to hydrofluoric acid fumes sufficient to cause pain requires immediate hospitalization for monitoring for pulmonary edema.

6. Spill disposal procedures

Overview: Evacuate area if fire is present or likely. Spills of this electrolyte from cells pose a risk to the safety of responders if water is present. Contact with water causes the production of extremely toxic and corrosive hydrofluoric acid. Remove all sources of ignition. Electrolyte will remove or soften painted surfaces causing slipperiness to be a hazard.

Personal precautions: For all spills, protect skin and eyes from contact with electrolyte. In all cases, wear self-contained breathing apparatus.

Environmental precautions: Prevent from migration into natural waterways. Absorb spilled material with non-reactive absorbent such as vermiculite, clay or earth.

Cleanup Procedures: Evacuate spill area immediately and remove sources of ignition. Do NOT touch spilled material. Cleanup personnel must be trained in the safe handling of this product. If possible ventilate area by means of non-sparking, grounded ventilation system. Spills may be absorbed on non-reactive absorbents such as vermiculite. Place cells into individual plastic bags and then place into appropriate containers and close tightly for disposal. Ensure that cleanup procedures do not expose spilled material to any moisture. Immediately transport closed containers outside.

Lined steel drums are suitable for storage of damaged cells until they can be proper disposal can be arranged.

December 31,2009 7.Safe Handling and storage procedures

Handling Procedures: This product is flammable and corrosive. Reaction products with water are also toxic.

Eliminate all ignition sources, (e.g. sparks, open flames, hot surfaces). Keep away from heat. Post "NO-SMOKING" signs. It is very important to keep areas where this material is used clear of other materials which can burn (e.g., cardboard, sawdust).

Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas of use. T o prevent sparking, generously wet hard surfaces before they are chipped, ground, etc, in potentially hazardous areas. Keep aisles and exits free of obstruction. Do not use with incompatible materials such as water, strong oxidizing agents, strong reducing agents, strong acids and strong alkalis. A void generating vapour or mists. Prevent the release of vapour and mists into the workplace air. T o avoid splashing, carefully dispense into sturdy containers made of compatible materials. Never transfer liquids by pressurizing the original shipping containers with air or inert gas. Do not dispense in storage area unless dispensing area is segregated by fire-resistant construction. Ground all drums, transfer vessels, hoses and piping. Ground clips must contact bare metal. When dispensing in other than a closed system, ensure dispensing container is bonded to receiving transfer equipment and container. Never return contaminated material to its original container. Label containers. Keep containers closed when not in use. A void damaging containers. Empty containers may contain hazardous residues.

Storage: Store in a cool, dry, well-ventilated area, out of direct sunlight and away from heat and ignition sources. Keep storage area clear of burnable materials (e.g. old rags, cardboard). Lighted cigarettes, matches, or any other ignition sources should not be allowed around indoor or outdoor storage areas. Inspect all incoming containers to make sure they are properly labeled and not damaged. Keep quantity stored as small as possible. Store away from water, strong oxidizing agents, strong reducing agents, strong acids and strong alkalis. Store in suitable, labeled containers (usually the shipping container). Keep containers tightly closed. A void stacking of containers. Protect from damage. Keep empty containers in separate storage area. Empty containers may contain hazardous residues. Keep closed. Store small quantities in approved fireproof flammables cabinet or storage room. Store flammable materials according to occupational health and safety regulations and fire and building codes, which will describe the kind of storage area and the type of storage containers for a specified amount of the material.

Store in an isolated fireproof building, if possible. Ground floor storage facilities are usually recommended. Storage facilities should be made of fire resistant materials. Use a grounded,

non-sparking ventilation system, approved explosion-proof equipment and intrinsically safe electrical systems. Store within temperature range recommended by electrolyte manufacturer/supplier.

Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Keep storage area separate from work areas. Store away from work process and production areas, elevators, building and room exits or main aisles leading to exits. Post warning signs. Inspect periodically for damage or leaks. Have appropriate fire extinguishers and spill clean-up equipment in or near storage area.

December 31,2009 8.Exposure controls procedures

Engineering control:General ventilation under normal use conditions.

Control parameters

8-Hour TWAs:None

Short-term exposure limits:None

Maximum exposure limits:None

Biological mark:None

Personal protective equipment

Respiratory protection:None under normal use conditions.

Hand protection:None under normal use conditions.

Eye protection:None under normal use conditions. Wear safety glasses when handling leaking batteries.

Skin and body protection:None under normal use conditions. Use butyl gloves when handling leaking batteries.

Othe r:Keep batteries away from small children..

Hygiene methods:Use water cleaning-up.

9.Physical and chemical properties

Physical phase:Solid

Color:Contents silver in color. Odor:None

Boiling point/boiling range:170 – 190 ℃Melting point:-25 - -35 ℃

PH value:NA Decomposition temperature:NA ℃

Flash point:NA ℃T est method:Open cup Close cup Ignition temperature:NA ℃Explosion limits (LEL) NA % (UEL) NA % V apor pressure:1.1-1.3 kPa @ 20o C V apor density:3.5

Relative Density:1.2 kg/litre Solubility:Miscible in water

10.Stability and reactivity

Stability:Stability

Possible hazardous reactions occurring under specific conditions:

Contents incompatible with strong oxidizing agents.

Conditions to avoid:Does not water, heat, crush, disassemble or short circuit.

Materials to avoid:W ater, heat, acid material.

Hazardous decomposition products:

Hydrogen Fluoride, Phosphorus Oxides, Carbon Monoxide, Carbon Dioxide, Lithium Hydroxide, Cobalt Oxides, Aluminium Oxide, possible fluoro-compounds, Carbon soot.

11.Toxicological information

Acute toxicity:None

Local effects:None

Sensitization:None

Chronic toxicity or long term toxicity:None

December 31,2009 Specific effects:None

12.Ecological information

Possible environmental effects/environmental mobility:

Abandons the battery to bury underground possibly creates the subsoil and the ground water pollution. These batteries pass the U. S. EP A's T oxicity Characteristic Leaching Procedure and therefore, may be disposed of with normal waste.

Environmental toxicity: No data available.

Biodegradability: No data available.

13.W aste disposal procedures

W aste disposal procedures:Always consult and obey all international, federal, provincial/state and local hazardous waste disposal laws. Some jurisdictions require recycling of this spent product.

Canadian Environmental Protection Act: Spent cells are not considered hazardous waste. Cells involved in a fire may be considered to be hazardous waste. Comply with all provincial and local regulations.

Resource Conservation and Recovery Act (RCRA): Spent cells are not considered hazardous waste. Cells involved in a fire may be considered to be hazardous waste. Comply with all state and local regulations.

14.Transport information

Canadian Transportation of Dangerous Goods Regulations: These cells have passed the tests listed in the United Nations Manual of T ests and Criteria, Part 38.3. Not regulated for transport under Special Provision 34 of the Canadian Transport of Dangerous Goods Regulations

United States Hazardous Materials Regulations (49 CFR): These cells have passed the tests listed in the United Nations Manual of T ests and Criteria, Part 38.3. Not regulated for transport by Special Provision 188 of the United States Code of Federal Regulations Title 49.

International Air Transport Association (IA TA): These cells have passed the tests listed in the

United Nations Manual of Tests and Criteria, Part 38.3. The outside of each package that contains

Lithium Cells/Batteries must be marked. The text: “Not Restricted” additional handling information on the air waybill. These cells must be packaged in accordance with Packing instruction Section II of PI965.

The cells or batteries for air shipment must comply with Section II of PI 965 accordingly as “Not

Restricted” Cargo:

For cells, the watt-hour rating should not be more than 20Wh.

For batteries, the watt-hour rating should not be more than 100Wh.

Each cell or battery is of the type proven to meet the requirements of each test in the UN Manual of Test and Criteria, Part Ⅲ, subsection 38.3.

December 31,2009 Packing requirements:

General packing requirement: Cells and batteries must be packed in strong outer packaging that

conform to 5.0.2.4, 5.0.2.6.1 and 5.0.12.1.

Additional requirements:

1) Cells and batteries must be packed in inner packaging that completely enclose the cell or

battery.

2) Cells and batteries must be protected so as to prevent short circuits.

3) Each package must be capable of withstanding a 1.2m drop test in any orientation without

damage to cells or batteries contained therein, shifting of the contents so as to allow battery to

battery contact and release of contents.

Each package must be labeled with a lithium battery handling label.

Limitation of weight:

Quantity per package for both Passenger Aircraft and Cargo Aircraft can only have 10Kg in gross

weight.

Overpacks: Individual packages each complies with the requirements of part 1 may be placed in an overpack. An over-pack must be marked with the W ord “Overpack” and labeled with the

lithium battery label, unless the labels on the package inside the overpack are visible.

By complying with the requirements specified above, Lithium ion cells and batteries are not otherwise regulated as Dangerous Goods.

International Maritime Organization (IMO): These cells have passed the tests listed in the United Nations Manual of Tests and Criteria, Part 38.3. Not regulated for transport under Special Provision 188 of the International Maritime Dangerous Goods Code (IMDG).

UN 3480 - Lithium ion batteries

UN 3481 - Lithium ion batteries packed with equipment/Lithium ion batteries contained in equipment Any Lithium ion cells or batteries subsequently repackaged or reshipped are required to meet all of the requirements specified above.

15.Regulatory information

Applicable regulations:

Local hazardous waste disposal laws.

This product is made from materials with no detectable mercury.

Canadian Federal Regulations:

Canadian Environmental Protection Act: All ingredients in the electrolyte are on the Domestic Substances List.

WHMIS Classification: Not controlled, manufactured article

United States Federal Regulations:

T oxic Substances Control Act: All ingredients are listed in the inventory.

OSHA: Does not meet criteria as per Part 1910.1200, manufactured article.

December 31,2009 CERCLA: Does not meet criteria

SARA 313: Does not meet criteria

SARA 311/312 EP A Hazard Categories: Does not meet criteria

EU Regulations

EINECS: Not applicable

EU Classification: Not classifiable

Labels: None

16.Other information

Literature references:

1) Local waste disposal laws.

2) The UN Manual of T ests and Criteria

3) 2008The Emergency Response Guidebook

4) 51th IA T A DANGEROUS GOODS REGULA TIONS

Name:E-ONE MOLI ENERGY CORP.

Organization

T elephone:886-6-5050666 # 2864

Address:No.10 Dali 2nd Rd., Shan-Hwa, Tainan County, T aiwan R.O.C.

Job title:SHE Chief Name (signature):Kuen-Huei Lin

Data Created:Dec 31,2009

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