PA10T材料物性表

P ROVISIONAL D ATA S HEET

G RIVORY HT

G RIVORY XE 4027

BLACK 9916

Product description

Grivory XE 4027 black 9916 is a 30% glass-fibre reinforced flame retardant (UL 94 V-0) engineering thermoplastic material based on a semicrystalline, partially aromatic co-polyamide.

Grivory XE 4027 black 9916 is free of halogens and red phosphorus.

RoHS: Grivory XE 4027 black 9916 is in compliance with RoHS (2002/95/EC, Re-striction of Hazardous Substances). WEEE:Parts produced from Grivory XE 4027 black 9916 are not subject to "selec-tive treatment" according the Directive 2002/96/EC on Waste Electrical and Elec-tronic Equipment.

ISO polymer designation: PA 10T/X

ASTM designation: PPA, polyphthalamide The main distinguishing features of Grivory HT-PPA, when compared to other poly-amides, are its good performance at high temperatures providing parts which are stiffer, stronger, have better heat distortion and dimensional stability as well as excel-lent chemical resistance and low moisture absorption.

Grivory XE 4027 black 9916 is especially suitable for injection moulded components in electrical and electronic applications which require a flame class acc. UL 94 V-0. The material is suitable for lead-free SMT reflow soldering acc. i.e. JEDEC J-STD-020C (peak temperature 260°C). Compo-nents conforming to JEDEC MSL1 are achievable.

PROPERTIES

Mechanical Properties Standard Unit State Grivory XE 4027

black 9916

Tensile E-modulus 1 mm/min ISO 527 MPa dry

cond.

10'000

10'000

Tensile strength at break 5 mm/min ISO 527 MPa dry

cond.

115

110

Elongation at break 5 mm/min ISO 527 % dry

cond.

1.5

1.5

Impact strength Charpy, 23°C ISO 179/2-1eU kJ/m2dry

cond.

35

35

Impact strength Charpy, -30°C ISO 179/2-1eU kJ/m2dry

cond.

35

35

Notched impact strength Charpy, 23°C ISO 1792-/1eA kJ/m2dry

cond.

6

6

Notched impact strength Charpy, -30°C ISO 179/2-1eA kJ/m2

cond. 6

Ball indentation hardness ISO 2039-1 MPa dry

cond.

225

225

Thermal Properties

Melting point DSC ISO 11357 °C dry 295 Heat deflection temperature HDT/A 1.80 MPa ISO 75 °C dry 265 Heat deflection temperature HDT/C 8.00 MPa ISO 75 °C dry 175 Thermal expansion coefficient long. 23-55°C ISO 11359 10-4/K dry 0.2 Thermal expansion coefficient trans. 23-55°C ISO 11359 10-4/K dry 0.65 Maximum usage temperature long term ISO 2578 °C dry 150

Electrical Properties

Dielectric strength IEC 60243-1 kV/m

m

dry

cond.

33

33

Comparative tracking index CTI IEC 60112 - cond. 600

Specific volume resistivity IEC 60093 ? · m dry

cond.

109

109

Specific surface resistivity IEC 60093 ?cond. 1011

General Properties

Density ISO 1183 g/cm3 dry 1.41 Flammability (UL 94) 0.4 - 3.2 mm ISO 1210 rating - V-0

IEC GWFI IEC 60695-2-12 °C - 960 Glow wire temperature (3mm)

IEC GWIT IEC 60695-2-13 °C 775 Water absorption 23°C/saturated ISO 62 % - 1.5 Moisture absorption 23°C/50% r.h. ISO 62 % - 0.6 Linear mould shrinkage long. ISO 294 % dry 0.3 Linear mould shrinkage trans. ISO 294 % dry 1.0 Product nomenclature acc. ISO 1874: PA 10T/X, MHF, 11-100, GF30

Information on Injection Moulding of

Grivory XE 4027 black 9916

This technical data sheet for Grivory XE 4027 black 9916 provides you with useful information on material preparation, machine requirements, tooling and processing.

MATERIAL PREPARATION

Grivory XE 4027 black 9916 is delivered dry and ready for processing in sealed packaging. Pre-drying is not necessary.

Storage

Sealed, undamaged bags can be kept over a long period of time in storage facilities which are dry, protected from the influence of weather and where the bags can be protected from damage.

Handling and Safety

Detailed information can be obtained from the material safety data sheet (MSDS) which can be requested with every material order.

Drying During its manufacturing process Grivory XE 4027 black 9916 is dried and packed with a moisture

content of ≤ 0.10%. Should the packaging become damaged or the material is left open too long, then the material must be dried. A too high moisture content can be shown by a foaming melt and silver streaks on the moulded part. The drying can be done as follows:

Temperature max. 80°C

Time 4 - 12 hours

Dew point -40°C

Temperature max. 100°C

Time 4 - 12 hours

Drying time If there is only little evidence of foaming of the melt or just slight silver streaks on the part, then the above mentioned minimal drying time will be suffi-cient. Material, which is stored open over days shows strong foaming, unusually easy flowing, streaks and rough surface on the moulded part. Then the maximal drying time is required.

Silver streaks can also be caused by overheating of the material (over 350°C) or by too long melt residence time in the barrel.

Drying temperature

Polyamides are affected by oxidation at tempera-tures above 80°C in the presence of oxygen. Visible yellowing of the material is an indication of oxida-tion. Hence temperatures above 80°C for desiccant dryers and temperatures above 100°C for vacuum ovens should be avoided. In order to detect oxida-tion it is advised to keep a small amount of granu-late (light colour only !) as a comparison sample.

At longer residence times (over 1 hour) a hopper dryer (80°C) is useful.

Use of Regrind

Grivory XE 4027 black 9916 is a thermoplastic material. This allows recycling of sprues, runners and rejected components in the running process

It is recommended to add a maximum of 25% re-grind as long as the requirements on the final part allow the addition of regrind.

To ensure a trouble free processing, special pre-caution has to be taken by the moulder. Following

points have to be kept in mind: ? Avoid moisture absorption of the regrind (oth-erwise drying is necessary)Contamination by foreign material such as other polymers, dust or oil has to be avoided Property and colour changes of the part can be controlled with proper handling measures. MACHINE REQUIREMENTS

Grivory XE 4027 black 9916 can be processed eco-nomically on all injection moulding machines suit-able for polyamides. Screw Wear and corrosion protected, 3-zone universal screws with check valves are recommended.

Length 18 D - 22 D Compression ratio 2 - 2.5

Screw Desiccant dryer Vacuum oven

Shot Volume

The metering stroke must be longer than the length of the check valve (without decompression dis-tance).

Shot volume = 0.5 - 0.8 x (max. shot volume)

Heating

At least three separately controllable heating zones, able of reaching cylinder temperatures up to 350°C are required. A separate nozzle heating is necessary. The cylinder flange temperature must be controllable (cooling).

Nozzle

Open nozzles are simple, allow an easy melt flow and are long lasting. There is, however, the danger that during retraction of the screw after injection, air maybe drawn into the barrel (decompression). For this reason, needle shut-off nozzles are often used.

Clamping Force

As a rule of thumb the clamping force can be esti-mated using the following formula:

TOOLING

The design of the mould tool should follow the general rules for glass fibre reinforced thermo-plastics.

For the mould cavities common mould tool steel quality (e.g. hardened steel) which has been hard-ened to level of 56 - 65 HRC is necessary. We recommend additional wear protection in areas of high flow rates in the tool (e.g. pin point gates, hot runner nozzles).

Demoulding / Draft Angle

Parts moulded from Grivory HT are setting very quickly showing excellent dimensional stability. Asymmetric demoulding and undercuts are to be avoided. It is favourable to foresee high numbers of large ejector pins or a stripper plate. Demoulding draft angles between 1 to 5° are acceptable. The following values can be considered:

(VDI 3400) 12 15

18 21 24 27 Depth of roughness (μm) 0.4 0.6 0.8 1.1 1.6 2.2 Demoulding angle (%) 1

1 1.1 1.

2 1.

3 1.5

(VDI 3400) 30 33 36 39 42 45 Depth of roughness (μm) 3.2 4.5 6.3 9 13 18 Demoulding angle (%) 1.8

2

2.5

3

4

5

Venting

In order to prevent burn marks and to improve the weld line strength, proper venting of the mould cav-ity should be provided. Venting channels on the parting surface with dimensions of depth 0.02 mm and width 2 - 5 mm are recommended.

Gate and Runner

To achieve an optimal mould-fill and to avoid sink marks, a central gate at the thickest section of the moulding is recommended. Pin point gate (direct) or tunnel gates are more economical and more com-mon with technical moulding.

To avoid premature solidification of the melt and difficult mould filling, the following points should be considered:

0.8 x thickest wall section of the injection

moulding part

1.4 x thickest wall section of the injection moulding part (but minimum 4 mm)

PROCESSING

Mould Filling, Post Pressure and Dosing

The best surface finish and a high weld line strength are achieved with a high injection speed and when a sufficiently long post pressure is em-ployed.

The injection speed should be chosen to be re-duced towards the end of the filling process in order to avoid overheating and burning. For dosing at low screw speed and pressure the cooling time should be fully utilised.

Selecting the injection unit Gate diameter

Runner diameter

Basic Machine Settings

In order to start up the machines for processing Grivory XE 4027 black 9916, following basic set-tings can be recommended:

Flange 80°C

Zone 1 305 - 320°C

Zone 2 305 - 320°C

Zone 3 305 - 320°C

Nozzle 305 - 320°C

Tool 110 - 150°C

Melt 300 - 330°C

Injection speed medium - high

Hold-on pressure (spec.) 500 - 800 bar

Dynamic pressure (hydr.) 5 - 15 bar

Peripheral screw speed 0.1 - 0.3 m/s Start-up and Purging

Foreign materials in the cylinder should be removed with suitable purging materials. Hot-runner systems should be purged likewise. Glass fibre reinforced polyamide 66 is a suitable “bridging material”. Cylinder heating should start with a clean, product-free screw, starting from the temperature level of the “bridging material” of 300°C up to the required temperature level of 300-330°C (see processing data).

After at least three full dosings (free-shots) - apply-ing the shortest possible residence time - the start up procedure can be implemented.

After completion of production with Grivory HT the screw, cylinder and melt distribution system should be cleaned out thoroughly.

Conditioning

The dimensions and the mechanical properties of Grivory HT products are only marginally influenced by moisture absorption. For testing purposes, parts can be stored in a climatic chamber until an in-crease in weight of 1 % has been achieved. In order to avoid stress through swelling, conditioning in hot water is to be avoided. CUSTOMER SERVICES

EMS-GRIVORY is a specialist for polyamide syn-thesis and polyamide processing. Our customer services are not only concerned with the manufac-turing and supply of engineering thermoplastics but also provide a full of technical support program: ? Rheological design calculation / FEA

? Prototype tooling

? Material selection

? Processing support

? Mould and component design

We are happy to advise you. Simply call one of our sales offices.

The recommendations and data given are based on our experience to date, however, no liability can be assumed in connection with their usage and processing.

Generated / updated: SEK / 07.2008

This version replaces all previous product specific data sheets.

https://www.wendangku.net/doc/0511966343.html,

Temperatures Speeds / Pressures

物性材料表

特性Feature 耐高温、耐冲击、高流动性、尺寸稳定。High temperature resistance, impact resistance, high liquidity, dimension stability. 用途Use 电子、电器零件、汽车部件等。Electronic, electrical parts, auto parts, etc. 注塑条件Injection conditions 预干燥温度Pre-drying temperature 预干燥时间Pre-drying time 进料区温度Feed zone temperature 压缩区温度Compression zone temperature 熔融区温度Melting zone temperature 喷嘴温度Nozzle Temperature 模具温度Mold 注射压力Injection pressure 物理机械性能Physical and mechanical properties 项目Project 单位unit 试验方法Test method 数值Value 密度Density 熔点Melting point 成型收缩率Mold Shrinkage 吸水率（24小时，23℃）Water Absorption (24 hours, 23 ℃) 熔融指数Melt Index 阻燃等级Flame Rating 拉伸断裂强度Tensile Strength 拉伸模量Tensile modulus 断裂伸长率Elongation at break 弯曲强度Bending 弯曲模量Bending modulus 悬臂梁（无缺口）冲击强度Izod (unnotched) impact strength 悬臂梁缺口冲击强度Izod notched impact strength 洛氏硬度Rockwell hardness 热变形温度（0.45MPa）Heat Deflection Temperature（0.45MPa） Dielectric Strength 绝缘破坏强度 Arc resistance 耐电弧性 Dielectric Constant 介电常数 Dielectric Losses 介电损耗 Characteristics 特性 平衡吸湿量Moisture Absorption at Equilibrium 线性成型收缩率，横向Linear Mould Shrinkage, Transverse 断裂伸长率Elongation at Break 屈服伸长率Elongation at Yield

PA10T材料物性表

P ROVISIONAL D ATA S HEET G RIVORY HT G RIVORY XE 4027 BLACK 9916 Product description Grivory XE 4027 black 9916 is a 30% glass-fibre reinforced flame retardant (UL 94 V-0) engineering thermoplastic material based on a semicrystalline, partially aromatic co-polyamide. Grivory XE 4027 black 9916 is free of halogens and red phosphorus. RoHS: Grivory XE 4027 black 9916 is in compliance with RoHS (2002/95/EC, Re-striction of Hazardous Substances). WEEE:Parts produced from Grivory XE 4027 black 9916 are not subject to "selec-tive treatment" according the Directive 2002/96/EC on Waste Electrical and Elec-tronic Equipment. ISO polymer designation: PA 10T/X ASTM designation: PPA, polyphthalamide The main distinguishing features of Grivory HT-PPA, when compared to other poly-amides, are its good performance at high temperatures providing parts which are stiffer, stronger, have better heat distortion and dimensional stability as well as excel-lent chemical resistance and low moisture absorption. Grivory XE 4027 black 9916 is especially suitable for injection moulded components in electrical and electronic applications which require a flame class acc. UL 94 V-0. The material is suitable for lead-free SMT reflow soldering acc. i.e. JEDEC J-STD-020C (peak temperature 260°C). Compo-nents conforming to JEDEC MSL1 are achievable.

Sabic DX10311原料物性表

L NP* Thermocomp* Compound DX10311A sia Pacific: COMMERCIAL DX10311 is 30% glass fiber reinforced, impact modified polycarbonate resin. High flow and good ductility. T YPICAL PROPERTIES 1 TYPICAL VALUE UNIT STANDARD M ECHANICAL T ensile Stress, brk, Type I, 5 mm/min 117M Pa A STM D 638T ensile Strain, brk, Type I, 5 mm/min 2.6%A STM D 638T ensile Modulus, 5 mm/min 8330M Pa A STM D 638F lexural Stress 190M Pa A STM D 790F lexural Modulus 7670M Pa A STM D 790T ensile Stress, break, 5 mm/min 119M Pa I SO 527T ensile Strain, break, 5 mm/min 2.7%I SO 527T ensile Modulus, 1 mm/min 8260M Pa I SO 527F lexural Stress, yield, 2 mm/min 182M Pa I SO 178F lexural Stress, break, 2 mm/min 181M Pa I SO 178F lexural Modulus, 2 mm/min 7720M Pa I SO 178I MPACT Charpy Impact, unnotched, 23°C 57k J/m2I SO 179/2C Izod Impact, unnotched, 23°C 752J /m A STM D 4812 Izod Impact, notched, 23°C 196J /m A STM D 256 Charpy Impact, notched, 23°C 20k J/m2I SO 179/2C T HERMAL H DT, 0.45 MPa, 3.2 mm, unannealed 128°C A STM D 648 CTE, -40°C to 40°C, flow 1.9E-051/°C A STM E 831 CTE, -40°C to 40°C, xflow 6.4E-051/°C A STM E 831P HYSICAL S pecific Gravity 1.42-A STM D 792M old Shrinkage, flow, 3.2 mm (5)0.1 - 0.3%S ABIC Method M old Shrinkage, xflow, 3.2 mm (5) 0.2 - 0.4% S ABIC Method Melt Volume Rate, MVR at 300°C/5.0 kg 37 c m3/10 min I SO 1133 1) 2) PLEASE CONTACT YOUR LOCAL SALES OFFICE FOR AVAILABILITY IN YOUR AREA DISCLAIMER : THE MATERIALS AND PRODUCTS OF THE BUSINESSES MAKING UP THE SABIC INNOVATIVE PLASTICS Source, GMD, Last Update: COMPANY, ITS SUBSIDIARIES AND AFFILIATES ("SABIC IP"), ARE SOLD SUBJECT TO SABIC IP' S STANDARD CONDITIONS OF SALE, WHICH ARE INCLUDED IN THE APPLICABLE DISTRIBUTOR OR OTHER SALES AGREEMENT, PRINTED ON THE BACK OF ORDER ACKNOWLEDGMENTS AND INVOICES, AND AVAILABLE UPON REQUEST. ALTHOUGH ANY INFORMATION, RECOMMENDATIONS, OR ADVICE CONTAINED HEREIN IS GIVEN IN GOOD FAITH, SABIC IP MAKES NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (I) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE CONDITIONS, OR (II) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING SABIC IP MATERIALS, PRODUCTS, RECOMMENDATIONS OR ADVICE. EXCEPT AS PROVIDED IN SABIC IP' S STANDARD CONDITIONS OF SALE, SABIC IP AND ITS REPRESENTATIVES SHALL IN NO EVENT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS MATERIALS OR PRODUCTS DESCRIBED HEREIN.Each user bears full responsibility for making its own determination as to the suitability of SABIC IP' s materials, products, recommendations, or advice for its own particular use. Each user must identify and perform all tests and analyses necessary to assure that its finished parts incorporating SABIC IP materials or products will be safe and suitable for use under end-use conditions. Nothing in this or any other document, nor any oral recommendation or advice, shall be deemed to alter, vary, supersede, or waive any provision of SABIC IP' s Standard Conditions of Sale or this Disclaimer, unless any such modification is specifically agreed to in a writing signed by SABIC IP. No statement contained herein concerning a possible or suggested use of any material, product or design is intended, or should be construed, to grant any license under any patent or other intellectual property right of SABIC Innovative Plastics Company or any of its subsidiaries or affiliates covering such use or design, or as a recommendation for the use of such material, product or design in the infringement of any patent or other intellectual property right * LNP is a trademark of the SABIC Innovative Plastics Company * Thermocomp is a trademark of the SABIC Innovative Plastics Company ? 1997-2011 SABIC Innovative Plastics Company.All rights reserved T ypical values only. Variations within normal tolerances are possible for variose colours.All values are measured at least after 48 hours s torage at 230C/50% relative humidity. All properties, except the melt volume rate are measured on injection m oulded samples.All samples are prepared according to ISO 294. O nly typical data for material selection purpose.Not to be used for p art or tool design. 3) T his rating is not intended to reflect hazards presented by this or any o ther material under actual fire conditions.4) O wn measurement according to UL. 5) Measurements made from laboratory test coupon. Actual shrinkage may vary outside of range due to differences in processing conditions, equipment, part geometry and tool design. It is recommended that mold shrinkage studies be performed with surrogate or legacy tooling prior to cutting tools for new molded article.

锂电材料物性对比

电池材料厂家技术标准积累 深圳市贝特瑞 MSG-S(518) 负极石墨粒径：D10=9.764；D50=17.136um；D90=28.189；水分:0.039;碳含量:99.952;TAP密度;1.036 比表面 积:2.784；首次容量/效率:363.51/94.18 深圳市贝特瑞 518 负极石墨粒径：D10=9.862；D50=16.888um； D90=28.374；水分:0.04%; 碳含量:99.962; TAP密度;1.042% 比表面积:2.625；首次容量/效率:352.3/92.5% 深圳市贝特瑞 AG 负极石墨粒径：D10=7.137；D50=18.058um； D90=37.495；水分：0.035;碳含量：99.676;TAP密度：1.001 首次容量/效率:320.83/90.42% 深圳市贝特瑞 AG 负极石墨粒径：D10=7.53；D50=17.779um； D90=39.648；水分：0.041;碳含量：99.743;TAP密度：1.002 ，首次容量/效率:326.51/90.67% 深圳市贝特瑞 SAG-23 负极石墨粒径：D10=8.318；D50=21.097um； D90=47.119；水分：0.04；碳含量：99.925；TAP密度：1.021 ，比表面积:4.605；首次容量/效率:332.11/92.08 深圳市贝特瑞 818 负极石墨粒径：D10=11.453；D50=18.226um； D90=28.762；水分：0.036；碳含量：99.964;TAP密度：1.121 比表面积:1.947;首次容量/效率:364.63/95.29% 深圳市贝特瑞 818 负极石墨粒径：D10=10.859；D50=18.033um；

材料物性表

EXTRUSION APPLICATION

Introduction Responsible for a long line of accomplishments in outstanding engineering plastics, UBE NYLON products have won the trust and respect of users the world over. UBE NYLON – NYLON 6, NYLON COPOLYMERS – is in wide use throughout industry with their unique properties utilized to their fullest potential. UBE NYLON 6 has a number of excellent properties as follows: Excellent in impact strength and rigidity Having a smaller friction coefficient, thus excellent in abrasion resistance Excellent in resistance to oils, solvents and chemicals Superior in heat resistance Appropriate to mass production, contributing to cost reduction Summary 1. Introduction 2. Nomenclature 3. Monofilament Applications 4. Film Applications 5. TERPALEX Polyamide 6/66/12 Copolymer Nomenclature The first 2 digits in the code indicate the type of Polyamide. The third and fourth digits indicate the molecular weight level for 1000 series. In case of copolymer, the third digit shows the viscosity level. The co-polymerization ratio can be roughly calculated from the fourth digit multiplying by 5. “T” means the basic grade for monofilament application and the grade contain some additives for maintain good process stability and high trans-parency. In case of “MT”, means monomer con-taining grade offering good flexibility and softness. 10: Polyamide 6 homopolymer 50: Polyamide 6/66 copolymer 70: Polyamide 6/12 copolymer Ex. 1022FDX04: : c.a. 22 x 1,000 = 22,000 Ex. 5034MTX1: : level = 3 (high viscosity) : c.a. 80/20(4 x 5 = 20et%) : monomer-contain type 2 Introduction

常用材料的热物性参数

表1 各种金属的热物性值 温度 C 比热 cal/(g·C) 导热系数 cal/(cm·s· C) 密度(g/cm3)液相 线、固相线温度 (C) =7.88(20C) =7.3(1500C) =7.0(1600C) =7.86(15C) =7.86(15C) =7.85(15C) =7.85(15C) =7.83(15C)

续表1 各种金属的热物性值 温度 C 比热 cal/(g·C) 导热系数 cal/(cm·s· C) 密度(g/cm3)液相 线、固相线温度 (C) =7.73(15C) Ts=1488 T L=1497 =7.84(15C) T S=1420 T L=1520 =7.7(15C) 13.1Cr,0.5Ni T S=1399 T L=1454 =7.0(15C) 比热相对于 普通铸铁

=7.1(15C) 温度 C 比热 cal/(g·C) 导热系数 cal/(cm·s· C) 密度(g/cm3)液相 线、固相线温度 (C) =7.5~7.8(15C) =8.92 T S=T L=1083

s=2.70(15C) T S=T M=660.2 温度 C 比热 cal/(g·C) 导热系数 cal/(cm·s· C) 密度(g/cm3)液相 线、固相线温度 (C) s=1.74 T L=T S=651 s=6.09 T S=1395 T L=1427

表2 铸型的热物性计算公式

硅砂，干型，呋喃铸型600C以下 0.385<<0.494 0.0058

材料物性表

Product Data Sheet CHARACTERISTICS TEST METHOD Physical Properties Specific Gravity ASTM D792 1.20 1.20 Mould Shrinkage ASTM D9550.1-0.3%0.001-0.003in/in Mechanical Properties Tensile Strength ASTM D63890MPa 13050psi Flexural Strength ASTM D790125MPa 18125psi Flexural Modulus ASTM D7906500MPa 943ksi Notched Izod Impact Strength (3.2mm) ASTM D256 85 J/m 1.6 ft-lb/in Thermal Properties Heat Deflection Temperature @ 1.82MPa (264 psi) ASTM D648145°C 293°F Electrical Properties Surface Resistivity ASTM D2571E15ohms 1E15ohms Description: Glass Fiber Reinforced Polypropylene PPR 40G NC702 Product Code: 5218702Internal Code: NATURAL Colour: Maxxam TM NOMINAL VALUE (SI)NOMINAL VALUE (ENGLISH)Flammability Properties Flame Rating @ 0.8mm Internal HB HB Processing Conditions PP Barrel Temperature 200-240 °C 392-464°F Mould Temperature 30-60 °C 86-140°F Drying Temperature 80-85 °C 176-185°F Drying Time 2-3 Hour 2-3 Hour Injection Pressure Hold Pressure Screw Speed Back Pressure Rev #: 0, Revision Date: 6/8/2010 PRINTED IN SHENZHEN LHM 33587 Walker Road,Avon Lake,Ohio 44012, USA, Tel 1-440-930 1000 WHEN YOU HAVE QUESTION WITH ENGINEERING PLASTICS, WE COMPOUND THE ANSWER. No.1, Qihang Industrial Park,Haoxiang Road, Shajing Town, Baoan,Shenzhen, P.R.China,Tel:86-755-29692888MODERATE MED-HIGH MED-HIGH THIS IS NOT A PRODUCT SPECIFICATION LOW THE INFORMATION PRESENTED HEREIN IS PRESENTED IN GOOD FAITH AND TO THE BEST OF OUR KNOWLEDGE IS TRUE AND ACCURATE. IT IS INTENDED AS A GUIDE AND IS OFFERED FOR USE AT YOUR DISCRETION AND RISK. POLYONE DOES NOT GUARANTEE RESULT AND DISCLAIM ANY LIABILITY INCURRED IN CONNECTION WITH THE USE OF THE PRODUCTS DESCRIBED OR THE INFORMATION PRESENTED Tel: 86-755-29692888

物性表

Safety Data Sheet complies with:directive 91/155/EEC revision:2.0 ISO 11014-1:Safety data sheet for chemical products. revision date:02/02/1998date of issue: 26/02/1998 p 1. Product and company identification Product name:Stanyl ?Product code:TE250F3 Manufacturer: DSM Engineering Plastics P.O. Box 43,6130 AA Sittard The Netherlands Emergency number: The Netherlands +31 (0)46 4 76 55 55 2. Composition/Information on ingredients This chemical product is a preparation Chemical nature:(poly)amide PA 46CAS number:50327-22-5Components contributing to the hazard: The material contains Sb 2O 3 as a synergist with an average content of max. 7%. Sb 2O 3 is classified as a harmful (Xn) substance with a risk phrase R40 carcinogen class 3. However, the Sb 2O 3 is embedded in an impervious matrix of polymer and is therefore less biological available than the free Sb 2O 3 (see also Section 15). 3. Hazards identification Most important hazards:Hazard warning not required Specific hazards: Vapour and fumes released at elevated processing temperatures may be irritant for the eyes, the nose, the throat and the respiratory tract and in case of overexposure may cause nausea and headache. The material is not classified as being a dangerous preparation according to the EEC-Directive 88/379 and the subsequent amendments. See also Section 15.4. First-Aid measures Inhalation: When fumes of molten material have been inhaled;- Move person to fresh air as quickly as possible - rest in half upright position - loosen clothing - keep warm In case of respiratory problems move person to first aid station for medical treatment.Skin contact: Any molten material on the skin/burns should be cooled (off) as quickly as possible by means of cold water.Cover the wound with sterile cloth and move person to first aid station or hospital for medical treatment.Attention: never pull off the molten material from the wound.Eye contact: Any material entering the eye should be flushed out with copious volumes of water.Ingestion: No danger of toxicity, this material is biologically inactive (see also Section 11). 5. Fire-fighting measures Extinguishing media: Water, water/foam, CO 2, ABC fire extinguisher powder.Specific Hazards: Treat the material as a solid that can burn. Moulded parts or solid granules generally burn slowly with flaming drips.

常用塑胶原料之物性1

塑料原料之物性说明 一流动特性(FLOW PROPERTIES) 热塑性塑料成型过程一般需经历加热塑化, 流动成型和冷却固化三个基本步骤.所谓加热塑化就是经过加热使固体高聚物变成粘性流体; 流动成型是借助注射机或挤塑机的柱塞或螺杆的移动,以很高的压力将粘性流体注入温度较低的闭合模具内,或以很高的压力将粘性流体从所要求形状的口模挤出,得到连续的型材;冷却固化是用冷却的方法使制品从粘流态变成玻璃态.几乎所有高聚物都是利用其粘流态下的流动行为进行加工成型的.表征流动特性的物理量如下: 1.熔融指数值(MELT INDEX) 熔融指数是评价热塑性聚合物特别是聚烯烃的挤压性的一种简单而实用的方法,其定义为: 在一定温度下, 熔融状态的高聚物在一定负荷下, 十分锺内从规定直径和长度的标准毛细管中流出的重量.其一般在熔融指数仪中测定. 可挤压性是指聚合物通过挤压作用形变时获得形状和保持形状的能力, 研究聚合物的挤出性质能对制品的材料和加工工艺作出正确的选择和控制,通常条件下,聚合物在固体状态不能通过挤压而成型,只有当聚合物处于粘流态时才能通过挤压获得宏观而有用的形变.挤压过程中,聚合物熔体主要受到剪切作用,故可挤压性主要取决于熔体的剪切粘度和拉伸粘度.大多数聚物熔体的粘度随剪切力或剪切速率增大而降低.. 熔融指数仪测定在给定剪切力下聚合物的流动度,用定温下10分锺内聚合物从出料孔挤出的重量(克)来表示,其数值就称为熔融指数. 所以流动度,即熔融指数实际上反映了聚合物分子量的大小,分子量较高的聚合物更易于缠结,分子体积更大,故有较大的流动阴力,表现出较高的粘度和低的流动度,亦即熔融指数低. 由于荷重小(1.2kgf)通测定的MI值不能说明注射或挤出成型时聚合物的实际流动性能.但用[MI]值能方便地表示聚合物流动性的高低. 2. 粘度VISCOSITY ( Psi *S) 粘度是表征流动性的一种性能, 一般粘度越大, 流动性越差. 1)剪切粘度 对应于剪切流动,即速度梯度的方向与流动方向相垂直. 粘度对剪切速率具有依赖性. 测量方法: 一般由奥氏粘度计和乌氏粘度计进行测量. 影响剪切粘度的因素如下: a)聚合物本身结构 粘度随分子量的增加而提高. b)温度 随温度升高, 粘度呈指数函数的方式降低. c)剪切速率 剪切速率增大, 粘度减小. d)剪切应力. 剪切应力增大, 粘度减小. e)压力 压力增大, 粘度增大.

PVC物性表

物质安全资料表 一．物品与厂商资料：物品名称：ＰＶＣ塑胶物品编号：无资料 制造商或供应商名称：XXXXXXX塑胶有限公司联系电话：0769-XXXXXXXx 二．成分辨识资料 成分名称ＰＶＣ粉45-60可塑剂18-30填充剂27-30安定剂 1.5-2.0滑　剂 0.5-1.0 三.危害辨识资料: 四.急救措施 不同暴露途径之急救方法:.吸入:未有资料 .皮肤接触:粉尘与颗粒触到皮肤用清洁剂与清水清洗,严重时送医治..食入:用手按喉吐出,严重时送医院治疗.最重要症状及危害效应:燃烧时产生氯化物对急救人员之防护:无资料对医师之提示:无资料五.灭火措施 适用灭火剂:二氧化碳 灭火时可能遭遇之特殊危害:防止口腔及眼睛长时间接触特殊灭火程序:无资料 消防人员之特殊防护设备:口罩和手套六.泄漏处理方法: 个人应注意事项:佩带口罩 手套环境注意事项:回收及收取飞散之物清理方法:设有良好的通风排气装置七.安全处置与储存方法: 处置:使用时不要品尝胶料味道,保持通风使空气循环 储存:1.储于阴凉、通风良好的的地区，远离热源、火花、火焰2.避免阳光直接照射，以免老化 物品危害分类:无含量(%)主要物质成分ＣＡＳ　ＮＯ．（化学文摘社登记号码） 主要症状:呕吐 ９００２-８６-２２６７６１-４０-０００４７１-３４-１００５５７-０５-１ 最重要危害效应健康危害效应:无 环境影响:环保产品 低铅低镉 物理性及化学性危害:燃烧时产生氯化物及轻微气味和粉尘 特殊危害:无

3.于其他可燃物隔离八.暴露预防措施：工程控制：无资料 控制参数：八小时日时平均容许浓度/短时间量平均容许浓度/最高容许浓度.呼吸防护：佩带口罩.手部防护：清水清洗 .眼睛防护：清水清洗，严重时送医院治疗 .皮肤及身体防护：清水清洗，严重时送医院治疗九.物理及化学性质十.安全性及反应性：安定性：安定 特殊状况下可能之危害反应：不会发生应避免之物质：强氧化剂、强酸、强碱危害分解物：氯化物十一.毒性资料：急毒性：无局部效应：无致敏感性：无 慢毒性或长期毒性：无资料特殊效应：无资料十二.生态资料： 不能弃于水域、林域地带，避免鸟鱼摄取十四.运输资料 国际运输规定：无资料联合国编号：无 国内运输规定：无资料特殊运输方法及注意事项： 避免同酸性物质一起运输，如发生意外而泄漏要立即收回十五.法规资料： 相关法规：消防法 卫生法十六.其他资料：参考文献 制表单位制表人 名称：XXXXXXXXXXXXX塑胶有限公司 地址： 职称： 姓名：熔点：130℃保存期：六个月蒸汽密度：无资料水中溶解度：不溶解 密度：1.3-1.5克每立方厘米物质状态：固体颜色：多色成型参考温度：170~180℃PH值：无 自然温度：常温蒸汽压：无资料、 形状：颗粒状气味：稍有异味

各种塑料基本物性表

塑膠原材料物性表 材料名稱密度收縮率成本USD/kg燃燒狀態料管溫度射出壓力 (Kg/cm2)模溫 (C°)用途ABS (BK) 1.42~2.4 ABS (HB COLOR) 1.05 1.42~1.75/450 ABS (HB GF10) 1.2 1.75~3.72/about 500 ABS (HB GF20) 1.220.002 2.19/60-80 ABS (HB GF30) 2.25~4.26/ ABS (Natural) 1.25~2.4/ ABS (PA/757BK) 1.53~1.75/ ABS (PA/765AB) 2.2/ ABS (V0 GF10) 1.2 3.86/about 500 ABS (V0) 1.05 1.42~2.11 ABS (透明) 1.96~2.06 ABS (Acrylonitrile Butadiene Styrene)丙烯睛-丁二烯-苯乙烯1.05~1.1 0.005 1.25~2.4 易燃, 暗黃,有黑煙. 軟 化.特有氣味. 硬, 脆. 金 屬聲 180~260450~210050~80 電器,日用品外殼,玩具,家具,運動用品,燈 飾,汽車配件 AS (GF20) 1.260.002210-28060-80 AS=SAN(Styrene-Acrylonitrile Copolymer)丙烯睛-苯乙烯1.06 0.004/190~280 700~2300 40~80 食具,日用品,透明裝飾面,主表面 EPS 發泡膠 Expanded PolyStyrene貨品包裝,絕緣板, 裝飾品 EVA 乙烯-醋酸乙烯共聚物. Ethlene-Vinyl Acetate Copolymer橡皮膠120~25030~50鞋底,吹氣玩具製品,包裝膠膜 HIPS (BW-4(H45))/ HIPS (HB) 高衝擊聚苯乙烯 High Impact PS/ 1.1~1.3/ HIPS (PA-765BK) 2.2耐沖擊.玩具,日用品,收音機殼,電視機殼. HIPS (V0)/ 1.55 PA +GF30 (V0)260~29050~90 PA 66 (HB)/250~31050~90噪音小,軟. 牙刷,線圈架, 拉絲,束帶,齒輪,電動玩具外殼,電器配件,運動用品 PC(GE10G15) 5.508/ PC(GF40) 1.820.15%270-31080-120 PC(HB) 3.63 PC(L-1250YN) 1.2 3.7/ PC(N) 聚碳酸脂. 防彈膠 Polycarbonate 1.2 0.60% 4.2~4.75 稍難燃, 黃色焰,黑煙. 軟化. 特有味 260~300 (330劣化) 700~2100 85~120 咖啡壺,電動工具外殼,安全頭盔,透明片, 防硬玻璃,電器零件 PC(透明) 4.0~4.2 PC+ABS 2.32~2.98 PC+ABS (FR2000, V0) 4.485215~240about 75060~80 PC+ABS (KU2-1468,V0)240~280about 75060~90 材料名稱密度收縮率成本USD/kg燃燒狀態料管溫度射出壓力 (Kg/cm2)模溫 (C°)用途 PE 聚乙烯1.14 0.45% 易燃, 尖端黃,下端藍. 邊滴邊燃. 石腊燃燒味170-25040-60 PE (Polyethlene)0.95 3.50%150-23020-40包裝膠袋,膠瓶,水桶,電線,大貨桶,玩具PE(High Density PE) 高密160~310700~140025~70包裝膠袋,膠瓶,膠花,電線,大貨桶,玩具PE(Low Density PE) 低密150~310600~140025~70包裝膠袋,膠瓶,水桶,電線,大貨桶

物性表

DuPont ? Zytel ? nylon resin Zytel ? 101L NC010 Value DAM 50%RH Identification Resin Identification ISO 1043PA66 Part Marking Code ISO 11469>PA66< Mechanical Yield Stress ISO 527MPa (kpsi) 82 (11.9)55 (8.0) Strain at Break ISO 527% 50mm/min 45 Nominal Strain at Break ISO 527%25>100 Yield Strain ISO 527% 4.525 Tensile Modulus ISO 527MPa (kpsi)3100 (450) 1400 (200) Tensile Creep Modulus ISO 899 MPa (kpsi) 1h 1400 (200) 1000h 820 (119) Poisson's Ratio 0.41 Flexural Modulus ISO 178MPa (kpsi)2800 (410) 1200 (174) Notched Charpy Impact Strength ISO 179/1eA kJ/m 2 -30°C (-22°F) 4.53 23°C (73°F) 5.515 Unnotched Charpy Impact Strength ISO 179/1eU kJ/m 2 -30°C (-22°F)400NB 23°C (73°F) NB NB Contact DuPont for Material Safety Data Sheet, general guides and/or additional information about ventilation, handling, purging, drying, etc.ISO Mechanical properties measured at 4.0mm, ISO Electrical properties measured at 2.0mm, and all ASTM properties measured at 3.2mm. Test temperatures are 23°C unless otherwise stated. The DuPont Oval Logo, DuPont?, The miracles of science? and Zytel? are trademarks or registered trademarks of DuPont Company. Copyright? 2005. 050630/050630 The information provided in this data sheet corresponds to our knowledge on the subject at the date of its publication. This information may be subject to revision as new knowledge and experience becomes available. The data provided fall within the normal range of product properties and relate only to the specific material designated; these data may not be valid for such material used in combination with any other materials, additives or pigments or in any process, unless expressly indicated otherwise. The data provided should not be used to establish specification limits or used alone as the basis of design; they are not intended to substitute for any testing you may need to conduct to determine for yourself the suitability of a specific material for your particular purposes. Since DuPont cannot anticipate all variations in actual end-use conditions DuPont makes no warranties and assumes no liability in connection with any use of this information. Nothing in this publication is to be considered as a license to operate under or a recommendation to infringe any patent rights. DuPont advises you to seek independent counsel for a freedom to practice opinion on the intended application or end-use of our products. Caution: Do not use this product in medical applications involving permanent implantation in the human body. For other medical applications see "DuPont Medical Caution Statement", H-50102. https://www.wendangku.net/doc/0511966343.html, Zytel ? 101L NC010 is a lubricated polyamide 66 resin for injection molding. Property Test Method Units