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土壤和地下水环境中胶体与污染物共迁移研究进展

2017年1月 CIESC Journal ·23·

January 2017第68卷 第1期 化 工 学 报 V ol.68 No.1

DOI :10.11949/j.issn.0438-1157.20161328

土壤和地下水环境中胶体与污染物共迁移研究进展

杨悦锁1,2,王园园1,宋晓明1,于彤2,杨新瑶1

(1沈阳大学区域污染环境生态修复教育部重点实验室,辽宁 沈阳 110044;

2吉林大学地下水环境与资源教育部重点实验室,吉林 长春 130021)

摘要:天然胶体在土壤和地下水环境中广泛存在。由于胶体不仅具有粒径小、比表面积大、表面带有电荷等基本

特点,而且具有独特的双电层结构和丰富的表面官能团,这些特点使得胶体成为地下环境中最为活跃的组分,并

对土壤与地下水中污染物的迁移产生重要影响。近年来,土壤与地下水环境中的胶体及其对污染物的促进迁移作

用受到越来越多研究者的关注。综述了地下环境中的胶体来源、可移动胶体的释放与沉积、胶体自身的特征与环

境行为以及胶体对不同污染物的促进迁移作用,分析了各种环境因子对胶体-污染物共迁移的影响。在此基础上,对地下环境中胶体与污染物共迁移的过程与机理等尚需深入研究的关键科学问题提出了研究展望。

关键词:地下水;胶体;土壤污染;共迁移;吸附;环境因子

中图分类号:X 142 文献标志码:A 文章编号:0438—1157(2017)01—0023—

14

Co-transport of colloids and facilitated contaminants in subsurface environment

YANG Yuesuo 1,2, WANG Yuanyuan 1, SONG Xiaoming 1, YU Tong 2, YANG Xinyao 1

(1Key Laboratory of Regional Environment and Eco -restoration , Ministry of Education , Shenyang University , Shenyang 110044, Liaoning , China ;2Key Laboratory of Groundwater Environment and Resources , Ministry of Education , Jilin University ,

Changchun 130021, Jilin , China )

Abstract : Natural colloids in the soil and groundwater environments are ubiquitous. Since colloids possess not only small particle size, greater specific area and surface-charged, but also a unique double-layer structure and rich surface functional groups, which make them the most active components in subsurface environment and play an important role on contaminants transport in soil and groundwater. The colloids facilitated contaminant transport in soil and groundwater environment has drawn much attention in recent years. This paper reviews the sources, release/deposition, characteristics of colloids and their environmental behavior in subsurface environment, as well as the colloids facilitated transport of different contaminants, and analyzes various environmental factors on co-transport of contaminants with colloids. The key scientific questions, further prospective of processes and mechanism of co-transport of contaminants with colloids in subsurface environment are then proposed.

Key words: groundwater; colloids; soil pollution; co-transport; adsorption; environmental factors

引 言 土壤和地下水环境(以下简称“地下环境”,

subsurface environment )属于人类赖以生存的两大圈层——岩石圈和水圈的重要内涵,包括表土层、

包气带和饱水带,其物理、化学、生物(简称“物- 2016-09-21收到初稿,2016-10-29收到修改稿。

联系人:王园园。第一作者:杨悦锁(1962—),男,教授。

基金项目:国家自然科学基金项目(41272255, 41472237, 41471409);

辽宁省创新团队项目(LT201502);沈阳市科技计划项目(F14-133-9-00,

F15-113-9-00)。 Received date: 2016-09-21. Corresponding author: WANG Y uanyuan, Yuanyuan.Wang@https://www.wendangku.net/doc/4f2567594.html, Foundation item: supported by the National Natural Science Foundation of China (41272255, 41472237, 41471409).

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